Co-Mn mineralisations in the ni laterite deposits of Loma Caribe (Dominican Republic) and Loma de Hierro (Venezuela)

dc.contributor.author Domènech, Cristina ca
dc.contributor.author Vilanova-de-Benavent, Cristina ca
dc.contributor.author Proenza, Joaquín A. ca
dc.contributor.author Tauler, Esperança ca
dc.contributor.author Lara, Laura ca
dc.contributor.author Galí, Salvador ca
dc.contributor.author Soler, Josep M. ca
dc.contributor.author Campeny, Marc ca
dc.contributor.author Ibáñez-Insa, Jordi ca
dc.contributor.other Consorci del Museu de Ciències Naturals de Barcelona ca
dc.date.accessioned 2025-11-05T13:06:09Z
dc.date.available 2025-11-05T13:06:09Z
dc.date.issued 2022-06-22
dc.description Cobalt demand is increasing due to its key role in the transition to clean energies. Although the main Co ores are the sediment-hosted stratiform copper deposits of the Democratic Republic of the Congo, Co is also a by-product of Ni–Co laterite deposits, where Co extraction efficiency depends, among other factors, on the correct identification of Co-bearing minerals. In this paper, we reported a detailed study of the Co mineralisation in the Ni–Co laterite profiles of Loma Caribe (Dominican Republic) and Loma de Hierro (Venezuela). Cobalt is mainly associated with Mn-oxyhydroxide minerals, with a composition between Ni asbolane and lithiophorite, although a Co association with phyllosilicates has also been recorded in a Loma de Hierro deposit. In Loma Caribe, Co-bearing Mn-oxyhydroxide minerals mainly developed colloform aggregates, and globular to spherulitic grains, while in Loma de Hierro, they displayed banded colloform, fibrous or tabular textures. Most of the compositional analyses of Mn-oxyhydroxides yielded 20 and 40 wt.% Mn, with Ni and Co up to 16 and 10 wt.%, respectively. In both profiles, Mn-bearing minerals were mainly found in the transition from the oxide horizon to the saprolite, as observed in other laterite profiles in the world, where the precipitation of Mn-bearing minerals is enhanced because of the pore solution saturation and pH increase.
dc.format application/pdf ca
dc.format.extent 26 p. ca
dc.identifier http://hdl.handle.net/2072/522735
dc.identifier https://doi.org/10.3390/min12080927
dc.identifier.citation Minerals 2022, 12, 927 ca
dc.identifier.entitat consorcis ca
dc.identifier.uri http://hdl.handle.net/11703/127801
dc.language eng ca
dc.provenance Recercat (Dipòsit de la Recerca de Catalunya) ca
dc.rights L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by/4.0/
dc.rights.accessrights info:eu-repo/semantics/openAccess ca
dc.subject Níquel
dc.subject Cobalt
dc.subject Manganès
dc.subject Metalls de transició
dc.subject Laterita
dc.subject Veneçuela
dc.subject República Dominicana
dc.subject Carib (Regió)
dc.subject 549
dc.subject.category Ciència i tecnologia ca
dc.subject.forma articles ca
dc.title Co-Mn mineralisations in the ni laterite deposits of Loma Caribe (Dominican Republic) and Loma de Hierro (Venezuela)
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/publishedVersion
dc.type.driver info:eu-repo/semantics/article ca
metadadalocal.dependencia 8008920

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